Powder coating aluminum intakes works well so I don’t see why it wouldn’t also work for the iron intakes. Just don’t get any powder coating on the inside of the manifold. It would be recommended to block the heat riser passage at the intake gasket though to keep from burning the powder coating on the intake manifold at the crossover passage.
As an alternative, I’ve had an iron intake ceramic coated in silver for my 272 over 21 years ago and it still looks good even at the still open heated crossover. Ceramic coatings are used on headers so I wasn’t worried with doing that on an intake.