As you've indicated, the original phenolic plastic spacer should be a better isolator of the carburetor from intake manifold heat than the aluminum spacer. It's interesting that both 1/2 inch spacers were used on different FoMoCo vehicles.
Once upon a time, in using a later 1.12 Autolite 4100 carb on a 'B' manifold, I found that the 1/2 inch thick aluminum spacer worked well as a carburetor to intake manifold adapter. Using a file, I tapered the throttle bores of the aluminum spacer so that the larger carb throttle plates would open.
NoShortcuts
a.k.a. Charlie Brown
near Syracuse, New York